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Synthesis of (-)-(1S,5R)- and (+)-(1R,5S)-trifluoroanalogues of frontalin

DOI: 10.1016/S0040-4039(99)01186-7

Source and publish data:

Tetrahedron Letters p. 6317 - 6320 (1999)

Update date:2022-07-30

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Authors:

Bravo, PierfrancescoBravo, Pierfrancesco

Corradi, EleonoraCorradi, Eleonora

Frigerio, MassimoFrigerio, Massimo

Meille, Stefano ValdoMeille, Stefano Valdo

Panzeri, WalterPanzeri, Walter

Pesenti, CristinaPesenti, Cristina

Viani, FiorenzaViani, Fiorenza

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Article abstract of DOI:10.1016/S0040-4039(99)01186-7

The synthesis of enantiomerically pure (-)-(1S,5R)-1-trifluoromethyl frontalin 7 starting from (-)-(1R)-menthyl (S)-toluene-4-sulfinate, 5- pentenylmagnesium bromide and methyl trifluoroacetate is described. The synthetic procedures to obtain the enantiom

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Full text of DOI:10.1016/S0040-4039(99)01186-7

Products guided by the article

Product name:(1'S/R,2S,RS)-2-trifluoromethyl-2-[1'-(4-methylphenyl)sulfinyl]pent-3'-enyloxirane

Cas No:248957-67-7

248957-67-7

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