Synthesis of (-)-(1S,5R)- and (+)-(1R,5S)-trifluoroanalogues of frontalin

DOI: 10.1016/S0040-4039(99)01186-7

Source and publish data:

Tetrahedron Letters p. 6317 - 6320 (1999)

Update date:2022-07-30

Topics:

Authors:

Bravo, Pierfrancesco

Corradi, Eleonora

Frigerio, Massimo

Meille, Stefano Valdo

Panzeri, Walter

Pesenti, Cristina

Viani, Fiorenza

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Article abstract of DOI:10.1016/S0040-4039(99)01186-7

The synthesis of enantiomerically pure (-)-(1S,5R)-1-trifluoromethyl frontalin 7 starting from (-)-(1R)-menthyl (S)-toluene-4-sulfinate, 5- pentenylmagnesium bromide and methyl trifluoroacetate is described. The synthetic procedures to obtain the enantiom

Full text of DOI:10.1016/S0040-4039(99)01186-7

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