Tetrahedron Letters p. 6677 - 6680 (1999)
Update date:2022-08-04
Topics: Organic synthesis Experimental terms
Bach, Jordi
Bull, Steven D.
Davies, Stephen G.
Nicholson, Rebecca L.
Sanganee, Hitesh J.
Smith, Andrew D.
N-acyl-5,5-dimethyl-oxazolidin-2-ones can function as versatile latent aldehyde equivalents - reductive cleavage with DIBAL-H affords aldehydes in good yield, while tandem DIBAL-H/Wittig methodology affords α,β-unsaturated esters.
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