Journal of Organometallic Chemistry p. 285 - 288 (1982)
Update date:2022-07-29
Topics:
Isnard, P.
Denise, B.
Sneeden, R. P. A
Cognion, J. M.
Durual, P.
Diethyl ketone, methyl ethyl ketone and dipropyl ketone may be formed, albeit in modest yields, by the ruthenium catalyzed hydroacylation of ethylene and propylene with propionaldehyde, acetaldehyde and butyraldehyde, respectively.The major side reactions consist of aldehyde Cannizzaro and Tishchenko-type transformations as well as aldolizations.Preliminary mechanistic studies have revealed the promoting influence of water in the formation of Ru-carboxylates, RuH(OCOC2H5)L3, from propionaldehyde and H2RuL4.
View MorePengchen New Material Technology Co., Ltd.
Contact:+86-512-63680537
Address:99.6 km of national road 318, Meiyan Community,Pingwang Town, Wujiang District, Suzhou 215225
website:http://www.konochem.com
Contact:86-29-86107037
Address:No.170 West Avenue,Xi’an 710082,China
China Synchem Technology Co.,Ltd
website:http://www.cnsynchem.com
Contact:+86-0552-4929311
Address:No.217 Daqing Road
website:http://www.antaibio.com
Contact:0086-21-65663057
Address:Room 2108, Building 2，No. 489 Zhengli Road，200433
Penglai Qianwei Chemical Co., Ltd.
Contact:86-535-3357802
Address:Shahelu (north), Penglai, Shandong, China
Doi:10.1021/ja01181a080
(1948)Doi:10.1016/j.tet.2018.04.055
(2018)Doi:10.1002/cmdc.201600248
(2016)Doi:10.1021/jo00837a613
(1970)Doi:10.1055/s-2000-6224
(2000)Doi:10.1007/BF00957365
()
