Inorganic Chemistry p. 437 - 445 (1965)
Update date:2022-08-05
Topics:
Endicott, John F.
Taube, Henry
Kinetic and stoichiometric measurements of the reductions of Ru(NH3)6+3 by Cr+2(aq) (Cl- independent as well as Cl- catalyzed paths) and stoichiometries of the reaction of Ru(NH3)5Cl+2 with Cr+2 are reported. Evidence is presented that the reduced species is in each case a Ru(II) ammine and that the ammine ligands remain in the Ru(II) coordination sphere for reasonable periods of time. The standard oxidation potential of Ru(NH83)6+2 = Ru(NH3)6+3 + e- has been determined as -0.214 v. Further kinetic studies of oxidation of Ru(II) species by ClO4- and Co(III) ammines are reported. Equilibrium quotients for the anation of Ru(NH3)5OH2+3 by Cl-, Br-, and I- have been determined taking advantage of the catalysis of the reactions by Ru(NH3)5OH2+2. Copyright 1965 by the American Chemical Society.
Ningbo Distant Chemicals Co.,Ltd
Contact:86-574-27862490,27862438
Address:5F-3,#54 DaShaNi street,Ningbo,CHINA
Contact:+91 - 22 - 26355700
Address:17, Lotus Business Park, Andheri West
Shanggao Ruiya Fine Chemicals Co., Ltd
Contact:+86-795-2592103
Address:Xingguang Nanlu,Shanggao County Industry Park
FOSHAN NANHAI ZHONGNAN PHARMACEUTICAL FACTORY
Contact:0086-0757-85609331
Address:XIAHENGTIAN INDUSTRIAL ZONE,SHAYONG VILLAGE,LISHUI TOWN
shanghai hekang chemical co.ltd
Contact:021-54173790
Address:328 WuHe Road, Building #A, 2nd Floor, Minhang, Shanghai 201109, China
Doi:10.1002/adsc.202001436
(2021)Doi:10.1021/acs.joc.8b01405
(2018)Doi:10.1016/S0040-4020(99)00890-X
(1999)Doi:10.1002/(SICI)1521-3773(19991203)38:23<3530::AID-ANIE3530>3.0.CO;2-W
(1999)Doi:10.1248/cpb.36.2423
(1988)Doi:10.1021/acs.orglett.8b01600
(2018)
