
Tetrahedron Letters p. 8365 - 8368 (1999)
Update date:2022-08-05
Topics:
Marinetti, Angela
Jus, Sebastien
Genet, Jean-Pierre
The bis-phosphetanes 1 and 2 have been used as chiral ligands in the rhodium-catalysed hydrogenations of dehydroamino acid derivatives. An unusual increase of the optical yields at high hydrogen pressures has been noticed. Mechanistic implications are dis
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Doi:10.1007/BF00470255
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(2000)