Towards the total synthesis of saponaceolides: Synthesis of cis-2,4- disubstituted 3,3-dimethylmethylenecyclohexanes

DOI: 10.1002/(SICI)1521-3773(19991216)38:24<3662::AID-ANIE3662>3.0.CO;2-1

Source and publish data:

Angewandte Chemie - International Edition p. 3662 - 3664 (1999)

Update date:2022-07-30

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Authors:

Trost, Barry M.

Corte, James R.

Gudiksen, Mark S.

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Article abstract of DOI:10.1002/(SICI)1521-3773(19991216)38:24<3662::AID-ANIE3662>3.0.CO;2-1

Controlling diastereoselectivity by metal coordination: In the case of 3,3-dimethylmethylenecyclohexanes 2 - a structural unit present in many interesting natural products - the thermodynamically less stable cis-2,4- disubstituted compounds become availab

Full text of DOI:10.1002/(SICI)1521-3773(19991216)38:24<3662::AID-ANIE3662>3.0.CO;2-1

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