Stereoselective SmI2-mediated conversion of carbohydrates into cyclopentanols

DOI: 10.1016/0040-4039(95)02380-1

Source and publish data:

Tetrahedron Letters p. 1305 - 1308 (1996)

Update date:2022-08-05

Topics:

Authors:

Grove, J.J. Cronje

Holzapfel, Cedric W.

Williams, D. Bradley G.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(95)02380-1

Carbohydrate derivatives were employed as precursors in the synthesis of stereodefined cyclopentanols. This rapid conversion was effected by a zinc-assisted Grob-fragmentation, followed by a stereocontrolled SmI₂-mediated cyclisation.

Full text of DOI:10.1016/0040-4039(95)02380-1

Products guided by the article

Product name:3,4-Di-O-benzyl-2,5,6-trideoxy-D-threo-hex-5-enose

Cas No:260265-64-3

R&D Labs maybe for 260265-64-3

Beijing Top Science biological technology co., LTD

Contact:+86-13439059536

Address:15-1705 jre three mile, Beijing 100000,CHINA
Allicon Pharmaceuticals,Inc.

Contact:+86-519-86339586，13584329896

Address:Changzhou Scientific and Education Park
Lonwin Chemical Group Limited

website:http://www.lonwinchem.com

Contact:Tel: 86-21-59858395

Address:No#966,Huaxu Road,Shanghai 201702,P.R.China
Shanghai Coupling Pharmaceutical R&D Co., Ltd.(expird)

Contact:+86 021 50106671

Address:403 Room No.4 Buiding, No. 526 Ruiqing Road, Shanghai Zhangjiang Hi-Tech Park
Shandong Hongxiang Zinc Co., Ltd

Contact:086-0311-66187879

Address:DaWang developing zone

Relevant to this article

Mechanistic study of the ring-enlargement reaction of (3-oxa-2-silacyclopentyl)methyl radicals into 4-oxa-3-silacyclohexyl radicals. Evidence for a pentavalent silicon-bridging radical transition state in 1,2-rearrangement reactions of β-silyl radicals

Doi:10.1021/ja993239s
(2000)
Synthesis of Palladium Complexes with ortho-Functionalized Aryl Ligands

Doi:10.1021/om9905963
(2000)
Synthesis of the pyridinyl analogues of dibenzylideneacetone (pyr-dba) via an improved Claisen-Schmidt condensation, displaying diverse biological activities as curcumin analogues

Doi:10.1039/c1ob06773g
(2012)
Crown-ether-modified cyclic dipeptides as supramolecular chiral catalysts

Doi:10.1080/10610278.2017.1392521
(2018)
Alumina-supported synthesis of antibacterial quinolines using microwaves

Doi:10.1016/S0968-0896(99)00256-4
(2000)
Concerning the reactivities of the C-1, C-2 and C-6 hydroxy groups of myo-inositol

Doi:10.1039/a907318c
(1999)

Article Doi