Stereoselective SmI2-mediated conversion of carbohydrates into cyclopentanols

DOI: 10.1016/0040-4039(95)02380-1

Source and publish data:

Tetrahedron Letters p. 1305 - 1308 (1996)

Update date:2022-08-05

Topics:

Authors:

Grove, J.J. Cronje

Holzapfel, Cedric W.

Williams, D. Bradley G.

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Article abstract of DOI:10.1016/0040-4039(95)02380-1

Carbohydrate derivatives were employed as precursors in the synthesis of stereodefined cyclopentanols. This rapid conversion was effected by a zinc-assisted Grob-fragmentation, followed by a stereocontrolled SmI₂-mediated cyclisation.

Full text of DOI:10.1016/0040-4039(95)02380-1

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