Stereoselective SmI2-mediated conversion of carbohydrates into cyclopentanols

DOI: 10.1016/0040-4039(95)02380-1

Source and publish data:

Tetrahedron Letters p. 1305 - 1308 (1996)

Update date:2022-08-05

Topics:

Authors:

Grove, J.J. Cronje

Holzapfel, Cedric W.

Williams, D. Bradley G.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(95)02380-1

Carbohydrate derivatives were employed as precursors in the synthesis of stereodefined cyclopentanols. This rapid conversion was effected by a zinc-assisted Grob-fragmentation, followed by a stereocontrolled SmI₂-mediated cyclisation.

Full text of DOI:10.1016/0040-4039(95)02380-1

Products guided by the article

Product name:3,4-Di-O-benzyl-2,5,6-trideoxy-D-threo-hex-5-enose

Cas No:260265-64-3

R&D Labs maybe for 260265-64-3

WENZHOU M&C FOREIGN TRADE CO.,LTD.

Contact:+86-577-88862917

Address:No.8 Liming West Road,Wenzhou,zhejiang,China
Nanjing Legend Pharmaceutical & Chemical Co., Ltd.

Contact:+86-25-83767696

Address:14-7 Zhongshan Lu Guluo District, Nanjing
Jiangsu Wanlong Chemical Co., Ltd.

website:http://www.wanlongchem.com

Contact:+86-511-86810993 0086-511-8681 0888;

Address:Quanzhou Town, Danyang City, Jiangsu
Hefei TNJ chemical industry co.,ltd

website:https://www.tnjchem.com

Contact:+86-551-65418695

Address:B911 Xincheng Business Center, Qianshan Road, Hefei Anhui China
Jiangsu Dacheng Pharmaceutical and Chemical Co.,Ltd

Contact:+86-0517-87036900

Address:Chuzhou Chemical park, Huai'an, Jiangsu Province

Relevant to this article

Mechanistic study of the ring-enlargement reaction of (3-oxa-2-silacyclopentyl)methyl radicals into 4-oxa-3-silacyclohexyl radicals. Evidence for a pentavalent silicon-bridging radical transition state in 1,2-rearrangement reactions of β-silyl radicals

Doi:10.1021/ja993239s
(2000)
Synthesis of Palladium Complexes with ortho-Functionalized Aryl Ligands

Doi:10.1021/om9905963
(2000)
Synthesis of the pyridinyl analogues of dibenzylideneacetone (pyr-dba) via an improved Claisen-Schmidt condensation, displaying diverse biological activities as curcumin analogues

Doi:10.1039/c1ob06773g
(2012)
Crown-ether-modified cyclic dipeptides as supramolecular chiral catalysts

Doi:10.1080/10610278.2017.1392521
(2018)
Alumina-supported synthesis of antibacterial quinolines using microwaves

Doi:10.1016/S0968-0896(99)00256-4
(2000)
Concerning the reactivities of the C-1, C-2 and C-6 hydroxy groups of myo-inositol

Doi:10.1039/a907318c
(1999)

Article Doi