Tetrahedron Letters p. 7147 - 7150 (1997)
Update date:2022-07-30
Topics:
Porter, John M.
Xuan, Xiangyang
Blackman, Burchelle
Hsu, Daniel
Fry, Albert J.
Anodic oxidation of 1,2-bis-(trimethylsilyl)-1,2-diphenylethane in methanol affords a 65:35 mixture of 1,2-dimethoxy-1,2-diphenylethane (dl:meso = 10:1 and diphenylacetaldehyde dimethylacetal. The results can be interpreted in terms of a 1,2-diaryl-2-methoxyethyl cation, which can undergo either nucleophilic attack by solvent or rearrangement to a 2,2-diaryl-1-methoxyethyl cation. Experiments testing the generality of the reaction are described.
View MoreChangzhou Screw International Trading Co., Ltd.
Contact:13906149256,18001495888
Address:Jiangsu，Jintanqu
Shanghai HengXun Pharmaceutical Tech. Co., Ltd.
Contact:86-86-52730756
Address:Room 603, No. 240, Tianmuzhong Road, Zhabei, Shanghai, China
Shijiazhuang Sdyano Fine Chemical Co., Ltd
Contact:+86-311-89830448
Address:NO.48 Ta Nan Road,Yuhua District,Shijiazhuang,Hebei,China
Chongqing maohuan Chemicals Co., Ltd
website:http://www.bschem.com
Contact:+86 13996103726
Address:Chongqing Nan'an District Tu Town
Shanghai Science Peptide Biological Technology Co.,ltd
website:http://www.scipeptide.com
Contact:+86-21-51099675
Address:No.8 Changyang Rd
Doi:10.1016/j.tetlet.2013.07.051
(2013)Doi:10.1016/S0022-328X(99)00664-6
(2000)Doi:10.1016/S0040-4020(00)00037-5
(2000)Doi:10.1021/ja00780a056
(1972)Doi:10.1002/jps.21952
(2010)Doi:10.1039/a906708f
(2000)
