Tetrahedron p. 9917 - 9926 (1995)
Update date:2022-07-30
Topics: Acetone Olefins Experimental terms Chemical terms Potassium permanganate Mediated radical reactions Chemoselective addition
Linker, Ursula
Kersten, Berthold
Linker, Torsten
A practical and efficient protocol for the radical addition of acetone (1) to olefins 2a-d, mediated by potassium permanganate, has been developed.The in situ generation of manganese(III) allows the chemoselective synthesis of saturated C-C bond formation products 4a-d in 39-58percent yield.Furthermore, the required amount of manganese is reduced drastically in account of the catalytic reaction cycle.
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