Tetrahedron Letters p. 511 - 514 (1982)
Update date:2022-09-26
Topics:
Lauzon, Guillaume de
Charrier, Claude
Bonnard, Hubert
Mathey, Francois
The protonation of phospholyl anions yields unstable 1-H-phospholes which spontaneously rearrange through 1,5-proton shifts to give 2-H-phospholes ; in turn these species undergo spontaneous Diels-Alder dimerization leading to P-P bonded <4+2>dimers.
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