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SELECTIVE CYCLOADDITION OF A COORDINATED CYCLIC TRIENE WITH ALKYNES. fORMATION OF BICYCLODECATRIENE SKELETON ON A Ru(0) TEMPLATE

DOI: 10.1246/cl.1983.499

Source and publish data:

Chemistry Letters p. 499 - 502 (1983)

Update date:2022-08-04

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Authors:

Itoh, KenjiItoh, Kenji

Mukai, KatsunoriMukai, Katsunori

Nagashima, HideoNagashima, Hideo

Nishiyama, HisaoNishiyama, Hisao

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Article abstract of DOI:10.1246/cl.1983.499

The 1,3,5-cyclooctatriene ligand of Ru(1-6-η-cyclooctatriene)-(1-2:5-6-η-cyclooctadiene) reacted with ethyne to yield Ru(η4,η2-bicyclo<4.2.2>deca-2,4,7-triene)(1-2:5-6-η-cyclooctadiene) by way of formal cycloaddition with high selectivity.Propyne or 1-butyne gave analogous bicyclodecatriene complexes.

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Full text of DOI:10.1246/cl.1983.499

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