Formation and Reaction of Acyl Substituted Nitrile Ylide through the Rh2(OAc)4-Catalyzed Reaction of α-Diazocarbonyl Compounds with Benzonitrile

DOI: 10.1246/cl.1992.2197

Source and publish data:

Chemistry Letters p. 2197 - 2200 (1992)

Update date:2022-08-02

Topics:

Authors:

Ibata, Toshikazu

Fukushima, Kazuaki

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1992.2197

The rhodium(II) acetate-catalyzed reaction of α-diazocarbonyl compounds with benzonitrile and dimethyl acetylenedicarboxylate gave oxazoles and pyrrole-3,4-dicarboxylates through the 1,5-cyclization and 1,3-dipolar cycloaddition of the acyl substituted nitrile ylide intermediates generated by the reaction of ketocarbenoids with benzonitrile.

Full text of DOI:10.1246/cl.1992.2197

Products guided by the article

Product name:3,4-Furandicarboxylic acid, 2-ethoxy-5-phenyl-, dimethyl ester

Cas No:28687-73-2

R&D Labs maybe for 28687-73-2

Hangzhou yi lu biont technology Co., LTD

Contact:+86-571-88152630

Address:Hangzhoushi HuafengRoad Yicheng3Building1001room.
C-LAB Chemievermittlung GmbH

Contact:+49-9398-993127

Address:Untertorstr. 27
Chemvon Biotechnology Co. Ltd.

website:http://www.chemvon.com

Contact:86-21-58550039;86-21-31268550-8004

Address:Suite B-10#, 6999 Chuansha Road, Pudong District, Shanghai 201202, China
GL Biochem (Shanghai) Ltd.

website:http://www.glschina.com

Contact:+86-21-61263310

Address:519 Ziyue Road, Shanghai, 200241, China.
Dezhou Longteng Chemical Co., Ltd.

website:http://www.sodium-methoxide.cn/

Contact:0086-18866052283

Address:Xinhua Industrial Zone, Dezhou City, Shandong Province, China

Relevant to this article

Chlorination of Conjugated Nitroalkenes with PhICl ₂and so ₂Cl ₂for the Synthesis of α-Chloronitroalkenes

Doi:10.1055/s-0040-1707396
(2020)
Palladium-catalyzed arylation of diisopropyl malonate applied to the efficient synthesis of the selective MMP inhibitor 5-(4-phenoxyphenyl)-5-[4-(2-pyrimidinyl)-1-piperazinyl]barbituric acid

Doi:10.3987/COM-05-S(T)40
(2006)
Semisynthesis of D-ring-modified taxoids: Thietane derivatives from taxine B

Doi:10.1016/S0040-4039(00)00727-9
(2000)
Antimalarial sulfide, sulfone, and sulfonamide trioxanes

Doi:10.1016/S0968-0896(00)00079-1
(2000)
Divergent routes to chiral cyclobutane synthons from (-)-α-pinene and their use in the stereoselective synthesis of dehydro amino acids

Doi:10.1021/jo991773c
(2000)
Phthalocyanine-centred and naphthalocyanine-centred aryl ether dendrimers with oligo(ethyleneoxy) surface groups

Doi:10.1016/S0040-4020(03)00436-8
(2003)

Article Doi