Formation and Reaction of Acyl Substituted Nitrile Ylide through the Rh2(OAc)4-Catalyzed Reaction of α-Diazocarbonyl Compounds with Benzonitrile

DOI: 10.1246/cl.1992.2197

Source and publish data:

Chemistry Letters p. 2197 - 2200 (1992)

Update date:2022-08-02

Topics:

Authors:

Ibata, Toshikazu

Fukushima, Kazuaki

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1992.2197

The rhodium(II) acetate-catalyzed reaction of α-diazocarbonyl compounds with benzonitrile and dimethyl acetylenedicarboxylate gave oxazoles and pyrrole-3,4-dicarboxylates through the 1,5-cyclization and 1,3-dipolar cycloaddition of the acyl substituted nitrile ylide intermediates generated by the reaction of ketocarbenoids with benzonitrile.

Full text of DOI:10.1246/cl.1992.2197

Products guided by the article

Product name:3,4-Furandicarboxylic acid, 2-ethoxy-5-phenyl-, dimethyl ester

Cas No:28687-73-2

R&D Labs maybe for 28687-73-2

Shanghai Mintchem Development ., Ltd

Contact:0086 21 5190 8570

Address:R602,4#,89Nong, Mudan Road Pudong Shanghai China
Shandong Yaroma Perfumery Co., Ltd.

Contact:+86- 531- 88024598

Address:7-702 Caizhi Central, 59 Gong Ye South Road, Jinan City,250101, P. R. China
Hangzhou Ledun Technology Co.,Ltd.

Contact:86-571-18767088918

Address:No.6 street,XiaSha,Hangzhou,China.
Dongguan Albiya Energy Science and Technology Co.,Ltd

Contact:+86-769-22181286

Address:Huanan Industial Park, Dongguan,China
GLD peptide scientific lnc.

Contact:21-7631221 15884421033

Address:326 Science and technology,Shanghai,China

Relevant to this article

Chlorination of Conjugated Nitroalkenes with PhICl ₂and so ₂Cl ₂for the Synthesis of α-Chloronitroalkenes

Doi:10.1055/s-0040-1707396
(2020)
Palladium-catalyzed arylation of diisopropyl malonate applied to the efficient synthesis of the selective MMP inhibitor 5-(4-phenoxyphenyl)-5-[4-(2-pyrimidinyl)-1-piperazinyl]barbituric acid

Doi:10.3987/COM-05-S(T)40
(2006)
Semisynthesis of D-ring-modified taxoids: Thietane derivatives from taxine B

Doi:10.1016/S0040-4039(00)00727-9
(2000)
Antimalarial sulfide, sulfone, and sulfonamide trioxanes

Doi:10.1016/S0968-0896(00)00079-1
(2000)
Divergent routes to chiral cyclobutane synthons from (-)-α-pinene and their use in the stereoselective synthesis of dehydro amino acids

Doi:10.1021/jo991773c
(2000)
Phthalocyanine-centred and naphthalocyanine-centred aryl ether dendrimers with oligo(ethyleneoxy) surface groups

Doi:10.1016/S0040-4020(03)00436-8
(2003)

Article Doi