Journal of Organometallic Chemistry p. 145 - 152 (1985)
Update date:2022-07-31
Topics:
Hutchinson, David W.
Semple, Graeme
Thallium(I) derivatives of esterified methylene bisphosphonates can be readily obtained by treating the latter with thallium(I) ethoxide under anhydrous conditions.Alkylation of the thallium(I) derivatives by a range of primary alkyl iodides takes place smoothly, and significantly higher yields are obtained than for the corresponding reactions with lithio or sodio derivatives.
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