Improved conditions for the Kiliani-Fischer synthesis

DOI: 10.1016/0040-4039(96)01270-1

Source and publish data:

Tetrahedron Letters p. 5893 - 5896 (1996)

Update date:2022-08-04

Topics:

Authors:

Adje Adje

Vogeleisen

Uguen Uguen

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Article abstract of DOI:10.1016/0040-4039(96)01270-1

DIBA-H reduction of O-TBDMS derivatives of cyanohydrins, followed by hydrolysis with a pH4 tartaric-buffer at low temperature produces the corresponding O-protected 2-hydroxy aldehydes in very high yields.

Full text of DOI:10.1016/0040-4039(96)01270-1

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