Improved conditions for the Kiliani-Fischer synthesis

DOI: 10.1016/0040-4039(96)01270-1

Source and publish data:

Tetrahedron Letters p. 5893 - 5896 (1996)

Update date:2022-08-04

Topics:

Authors:

Adje Adje

Vogeleisen

Uguen Uguen

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(96)01270-1

DIBA-H reduction of O-TBDMS derivatives of cyanohydrins, followed by hydrolysis with a pH4 tartaric-buffer at low temperature produces the corresponding O-protected 2-hydroxy aldehydes in very high yields.

Full text of DOI:10.1016/0040-4039(96)01270-1

Products guided by the article

Product name:((2R,3R,4S,5R)-3,5,6,6-Tetramethoxy-2,4-dimethyl-hexylsulfanyl)-benzene

Cas No:293745-33-2

R&D Labs maybe for 293745-33-2

qingdao goldenchem imp and exp co.,ltd.

Contact:532-55579246

Address:no.62 ,haier road laoshan distirct
Jinan Hongfangde Pharmatech Co.,Ltd

Contact:86-531-88870908

Address:F Bldg. West Unit North Area of Univ. Tech. Garden Xinyu Rd. Jinan New & High Tech Industry Development Zone Shandong, China
taizhou creating bio-pharm co.,ltd.

Contact:+86- 576- 88827176

Address:715 room ,unit A.junyue Building,Jiaojiang,Taizhou,Zhejiang,China
SAMWON INDUSTRIAL LIMITED

Contact:+86-25-84873444

Address:1108, BLDG B, New Century Plaza, No 1, South Taiping Rd.,
Exploiter Molybdenum Co.,Ltd

Contact:86-379-63338609

Address:Jiudian Village,Deting Town,Song County,Luoyang

Relevant to this article

Doi:10.1021/ja01537a016
(1958)
Ketone Formation from Carboxylic Acids by Ketonic Decarboxylation: The Exceptional Case of the Tertiary Carboxylic Acids

Doi:10.1002/chem.201702680
(2017)
Doi:10.1021/jo00940a016
(1974)
The synthesis and antibacterial activity of totarol derivatives. Part 3: modification of ring-B

Doi:10.1016/S0968-0896(00)00096-1
(2000)
An efficient copper-catalyzed homocoupling of terminal alkynes to give symmetrical 1,4-disubstituted 1,3-diynes

Doi:10.1002/adsc.201100035
(2011)
REACTIVITY OF ORGANO LITHIUM REAGENTS ON DIMETHYL SQUARATE: A 1,2-ADDITION PROCESS LEADING TO NEW 1-HYDROXY-3,4 DIMETHOXY 3-CYCLOBUTENONE

Doi:10.1016/S0040-4039(00)94759-2
(1985)

Article Doi