First method for the preparation of strongly electrophilic chiral sulfinimines, and applications in asymmetric synthesis

Article abstract of DOI:10.1080/10426509908546463

A new and preparatively useful method for the synthesis of non racemic α-trifluoromethyl α-amino acids is presented, using chiral sulfinimines of trifluoropyruvate as key-building blocks.

Full text of DOI:10.1080/10426509908546463

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Phosphorus, Sulfur, and
Silicon and the Related
Elements
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First Method for
the Preparation of
Strongly Electrophilic
Chiral Sulfinimines,
and Applications in
Asymmetric Synthesis
Pierfrancesco Bravo , Marcello Crucianelli &
Matteo Zanda
a C.N.R. – Centro di Studio sulle Sostanze
Organiche Naturali. Dip.to di Chimica del
Politecnico , via Mancinelli 7, 20131 Milano,
Italy
b C.N.R. – Centro di Studio sulle Sostanze
Organiche Naturali. Dip.to di Chimica del
Politecnico , via Mancinelli 7, 20131 Milano,
Italy
c C.N.R. – Centro di Studio sulle Sostanze
Organiche Naturali. Dip.to di Chimica del
Politecnico , via Mancinelli 7, 20131 Milano,
Italy
Published online: 17 Mar 2008.
To cite this article: Pierfrancesco Bravo , Marcello Crucianelli & Matteo
Zanda (1999) First Method for the Preparation of Strongly Electrophilic
Chiral Sulfinimines, and Applications in Asymmetric Synthesis, Phosphorus,

Sulfur, and Silicon and the Related Elements, 153:1, 345-346, DOI:
10.1080/10426509908546463
To link to this article: http://dx.doi.org/10.1080/10426509908546463
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