Journal of Organic Chemistry p. 3990 - 3995 (2017)
Update date:2022-07-31
Topics:
Companys, Simon
Pouységu, Laurent
Peixoto, Philippe A.
Chassaing, Stefan
Quideau, Stéphane
Two model ortho-quinol acetates were easily prepared by iodane-mediated acetoxylative phenol dearomatization and evaluated for their reactivity toward various aryl-based nucleophiles, i.e., aryl metallic reagents and phenolic derivatives. Novel modes of reactivity, allowing the formation of biaryl linkages, were revealed and here exploited for the synthesis of two natural phenolics.
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