ALKYLATION DIRECTE DE CETONES ET D'ALDEHYDES EN PRESENCE DE POTASSE SOLIDE EN SUSPENSION

DOI: 10.1016/S0040-4020(01)96749-3

Source and publish data:

Tetrahedron p. 5031 - 5038 (1985)

Update date:2022-08-03

Topics:

Authors:

Artaud, I.

Torossian, G.

Viout, P.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)96749-3

Dehydrated solid KOH, suspended in aprotic solvents, is used as a base for ketone and aldehyde alkylation.The best solvent as regards yields and selectivity is DME.The quantity of KOH depends on the carbonyl compound acidity.This method gives as good results as less convenient homogeneous conditions.

Full text of DOI:10.1016/S0040-4020(01)96749-3

Products guided by the article

Product name:2,2-diethylhexanal

Cas No:30857-73-9

R&D Labs maybe for 30857-73-9

ENERGYCO LTD.

Contact:+86-25-83719363

Address:106-7 Chunnan Rd, Chunxi Town, Gaochun, Nanjing, China
Xi'an Unique Electronic and Chemical Co., Ltd.

Contact:+86-029-88238008

Address:1703# B BUILDING WEST ELECTRONIC ZONE, XI'AN, CHINA
Qingdao XinYongAn Chemicals Co., Ltd

Contact:+86-532-81107967

Address:Chengyang dual-port industrial park by the sea，Qingdao
Jinhua City Mingzhu Pharmaceutical Co.,Ltd.

Contact:15857995878 0579-82207761

Address:No.169 Shenze Road, New Area,Jinpan Development Zone, Jinhua
Tosta Enterprise Co., Ltd.

Contact:+86-134-5286-9121

Address:Add: Wing Tuck Commercial Centre, 177-183 Wing Lok Street, Hong Kong,

Relevant to this article

Rhodium and iridium complexes with thiolate and tertiary phosphine ligands. the synthesis

Doi:10.1039/b005588n
(2000)
Rearrangement of Rigid Cyclopropylcarbinyl Radicals: Investigation of a Reporter System for the Detection of Very Short Lived Radicals

Doi:10.1021/jo00307a015
(1990)
Chlorocarbonyl ruthenium(II) complexes of tripodal triphos {MeC(CH₂PPh₂)₃}: Synthesis, characterization and catalytic applications in transfer hydrogenation of carbonyl compounds

Doi:10.1016/j.jorganchem.2010.01.011
(2010)
Supramolecular functionalization of single-walled carbon nanotubes (SWNTs) with dithieno[3,2- b:2′,3′-d ]pyrrole (DTP) containing conjugated polymers

Doi:10.1021/ma201610y
(2011)
Structure-based design and synthesis of lipophilic 2,4-diamino-6- substituted quinazolines and their evaluation as inhibitors of dihydrofolate reductases and potential antitumor agents

Doi:10.1021/jm980081y
(1998)
Synthesis of the Heptacyclic Indole Alkaloid (+/-)-Kopsine and Related Studies

Doi:10.1021/ja00199a033
(1989)

Article Doi