Oxidative coupling of phosphinomethanides at a metal centre: P-P vs. C-C bond formation and the molecular structure of the novel bis-ylide (Me 3Si)2C=PMe2-PMe2=C(SiMe 3)2

DOI: 10.1039/C39880000517

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 517 - 518 (1988)

Update date:2022-08-05

Topics:

Authors:

Karsch, Hans H.

Deubelly, Brigitte

Mueller, Gerhard

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/C39880000517

Metal induced coupling of [CH₂PMe₂]^- leads to Me₂PCH₂CH₂PMe₂, whereas coupling of [C(X)(SiMe₃)(PMe₂)]^- (X=SiMe₃ or PMe₂) results in P-P bond formation affording [(X)(SiMe ₃)C=PMe₂-]₂, with a central P-P bond of length 2.278(1) A.

Full text of DOI:10.1039/C39880000517

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Ni(P(CH₃)3)2((CH₃)2PCH₂CH₂P(CH₃)2)

Cas No:32237-68-6

R&D Labs maybe for 32237-68-6

Xi'an Kaixiang Photoelectric Technology Co., Ltd

website:http://www.kxmaterials.com/

Contact:86-29-15991651477

Address:Building 6, Biopharmaceutical Industry R&D Cluster Base, No. 16, Caotang 4th Road, Caotang Science and Technology Industrial Base, High-tech Zone, Xi'an City, Shaanxi Province, China
Zhejiang Sucon Silicone Co.,Ltd

Contact:+86-575-88046692

Address:Qisheng Rd., Paojiang Industrial Zone, Shaoxing, Zhejiang, China.
Shanghai agrotree chemical co.,ltd.

Contact:+86-21-50117563

Address:Room 8A,liangfeng building,No.8 dongfang RD.pudong,shanghai,China
MTT Pharma & Bio-technology Co.,Ltd(expird)

Contact:+86-21-58407925

Address:Room2019, Building C, Tomson Center, No.158, Zhang Yang Road, Shanghai, China
Lian Xing Chemical Co.,Ltd.

Contact:0792-8228321

Address:10TH Floor No.121 binjiang Road Xunyang District

Relevant to this article

Fluoride-mediated phosphination of alkenes and alkynes by silylphosphines

Doi:10.1016/j.tetlet.2004.10.098
(2004)
Ru@PsIL-Catalyzed Synthesis of N-Formamides and Benzimidazole by using Carbon Dioxide and Dimethylamine Borane

Doi:10.1002/cctc.201800185
(2018)
Carbon-carbon coupling in dinuclear cycloaurated complexes containing bridging 2-(diphenylphosphino)phenyl or 2-(diethylphosphino)phenyl. Role of the axial ligand and the fine balance between gold(II)-gold(II) and gold(I)-gold(III)

Doi:10.1021/om000773w
(2001)
Doi:10.1016/S0040-4039(01)96476-7
(1971)
The Paal-Knorr reaction revisited. A catalyst and solvent-free synthesis of underivatized and N-substituted pyrroles

Doi:10.1039/c4gc01523a
(2015)
New palladium complexes with rigid scorpion-type ligands. Crystal structure of complexes [Pd(η³-2-CH₃-C₃H ₄)(bpz*mPh)](CF₃SO₃) and [Pd(bpz*mpy)₂](BF₄)₂. bpz*mPh=phenyl-bis(3,5-dimethylpyrazol-1-yl)methane; Bpz*mpy=pyridin-2-yl-bis(3,5-dimethylpyrazol-1-yl)methane

Doi:10.1016/S0022-328X(00)00160-1
(2000)

Article Doi