Oxidative coupling of phosphinomethanides at a metal centre: P-P vs. C-C bond formation and the molecular structure of the novel bis-ylide (Me 3Si)2C=PMe2-PMe2=C(SiMe 3)2

DOI: 10.1039/C39880000517

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 517 - 518 (1988)

Update date:2022-08-05

Topics:

Authors:

Karsch, Hans H.

Deubelly, Brigitte

Mueller, Gerhard

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/C39880000517

Metal induced coupling of [CH₂PMe₂]^- leads to Me₂PCH₂CH₂PMe₂, whereas coupling of [C(X)(SiMe₃)(PMe₂)]^- (X=SiMe₃ or PMe₂) results in P-P bond formation affording [(X)(SiMe ₃)C=PMe₂-]₂, with a central P-P bond of length 2.278(1) A.

Full text of DOI:10.1039/C39880000517

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Ni(P(CH₃)3)2((CH₃)2PCH₂CH₂P(CH₃)2)

Cas No:32237-68-6

R&D Labs maybe for 32237-68-6

Zhejiang Sanmei Chemical Industry Co., Ltd

Contact:86-579-87633213

Address:Huchu Industrial Zone, Qingnian Rd., Wuyi County, Zhejiang Prov., China.
Henan Techway Chemical Co.,Ltd.

website:http://www.techwaychem.com

Contact:+86-371-66380080

Address:No.27 Shunhe Road,
Chengdu ZY Biochemical Technology Co., LTD

Contact:0086-28-88680086

Address:170 Qingpu Road, Shouan Town, Pujiang County
Henan Harvest Chem Co., Ltd

Contact:+86-371-86058576

Address:NO.32, Jingsan Road, Zhengzhou, China
Shanghai Bocimed Pharmaceutical Co., Ltd.

website:http://www.bocimed.com

Contact:+86-21-68861632

Address:Building 1, Lane 647, Songtao Road, Zhangjiang High-Tech Park, Shanghai

Relevant to this article

Fluoride-mediated phosphination of alkenes and alkynes by silylphosphines

Doi:10.1016/j.tetlet.2004.10.098
(2004)
Ru@PsIL-Catalyzed Synthesis of N-Formamides and Benzimidazole by using Carbon Dioxide and Dimethylamine Borane

Doi:10.1002/cctc.201800185
(2018)
Carbon-carbon coupling in dinuclear cycloaurated complexes containing bridging 2-(diphenylphosphino)phenyl or 2-(diethylphosphino)phenyl. Role of the axial ligand and the fine balance between gold(II)-gold(II) and gold(I)-gold(III)

Doi:10.1021/om000773w
(2001)
Doi:10.1016/S0040-4039(01)96476-7
(1971)
The Paal-Knorr reaction revisited. A catalyst and solvent-free synthesis of underivatized and N-substituted pyrroles

Doi:10.1039/c4gc01523a
(2015)
New palladium complexes with rigid scorpion-type ligands. Crystal structure of complexes [Pd(η³-2-CH₃-C₃H ₄)(bpz*mPh)](CF₃SO₃) and [Pd(bpz*mpy)₂](BF₄)₂. bpz*mPh=phenyl-bis(3,5-dimethylpyrazol-1-yl)methane; Bpz*mpy=pyridin-2-yl-bis(3,5-dimethylpyrazol-1-yl)methane

Doi:10.1016/S0022-328X(00)00160-1
(2000)

Article Doi