Solvent Effects on the Deacylation of Acylchymotrypsins: A Critical Comment on the Charge-Relay Hypothesis

DOI: 10.1021/ja00397a042

Source and publish data:

Journal of the American Chemical Society p. 1827 - 1831 (1981)

Update date:2022-08-05

Topics: Solvent Effects Deacylation

Authors:

Hamilton, Susan E.

Zerner, Burt

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Article abstract of DOI:10.1021/ja00397a042

The pH dependencies for deacylation of a series of acyl-chymotrypsins, prepared by using peptide-free enzyme, are reported.The pK_a' values exhibit considerable variation, from 7.63 for α-benzamide-trans-cinnamoyl-chymotrypsin to 6.6 for 3,5-din

Full text of DOI:10.1021/ja00397a042

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