Reaction of 2-Substituted Acrylonitriles with Diazoalkanes. Preparation of Cyclopropanone Cyanohydrins

DOI: 10.1021/jo00174a033

Source and publish data:

Journal of Organic Chemistry p. 5333 - 5337 (1983)

Update date:2022-07-29

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Authors:

Oku, Akira

Yokoyama, Taka-aki

Harada, Toshiro

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Article abstract of DOI:10.1021/jo00174a033

The preparation of cyclopropanone cyanohydrins was investigated.The reaction of 2-acetoxyacrylonitrile (1) with carbenes, e. g., diphenylcarbene, phenylcarbene, fluorenylidene, and methylene, gave the corresponding 1-acetoxy-1-cyanocyclopropanes (3).Simil

Full text of DOI:10.1021/jo00174a033

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