Journal of Organic Chemistry p. 8290 - 8299 (2015)
Update date:2022-09-26
Topics:
Wilson, Robert J.
Kaminsky, Lauren
Ahmed, Ijaz
Clark, Daniel A.
An efficient synthetic strategy for the regiospecific silylvinylation of internal alkynes is described. This transformation is catalyzed by RuHCl(CO)(SIMes)PPh3 and provides a net 5-exo-dig trans-silylvinylation of internal alkynes. Ethylene wa
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