Welcome to LookChem.com Sign In|Join Free

Article Doi

Pentamethylcyclopentadienyl ruthenium complexes with sulfur- and selenium-donor ligands

DOI: 10.1021/om010054x

Source and publish data:

Organometallics p. 3777 - 3781 (2001)

Update date:2022-07-29

Topics:

Authors:

Zhang, Qian-FengZhang, Qian-Feng

Cheung, Florence K.M.Cheung, Florence K.M.

Wong, Wai-YeungWong, Wai-Yeung

Williams, Ian D.Williams, Ian D.

Leung, Wa-HungLeung, Wa-Hung

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/om010054x

Treatment of [Cp*Ru(NO)Cl2] (Cp* = η5-C5Me5) with NaQAr or LiQAr (Q = S, Se, Te; Ar = C6F4H or Ph) affords [Cp*Ru(NO)(QAr)2]. Interactions of [Cp*Ru(NO)(SC6F4H)2] with PR3 (R = Ph or Me) give [Cp*Ru(PR3)2(SC6 F4H)] via phosphoraminate intermediates. The crystal structures of [Cp*Ru(NO)(SC6F4H)2] and [Cp*Ru(PMe3)2(SC6F4H)] have been determined. Treatment of [Cp*Ru(MeCN)3][PF6] with HN[SeP(i-Pr)2]2 affords a novel Cp*Ru(IV) complex, [Cp*Ru{η2-Se2P(i-Pr)2} {η2-SeP(i-Pr)2}][PF6], which has been characterized by X-ray crystallography.

View More

Full text of DOI:10.1021/om010054x

Products guided by the article

Product name:[(η5-C5Me5)Ru(PPh3)2(SC6F4H)]

Cas No:362060-41-1

362060-41-1

R&D Labs maybe for 362060-41-1

Relevant to this article

Hot Product