Iron-rhodium complexes with a single bridging diphosphine ligand: The crystal structure of [CpFe(μ-CO)2(μ-dppm)RhI2]

DOI: 10.1016/S0022-328X(96)06525-4

Source and publish data:

Journal of Organometallic Chemistry p. 255 - 258 (1996)

Update date:2022-08-05

Topics:

Authors:

Mansfield, Ian

Nawar, Nagwa

Smith, Anthony K.

Tong, Nicola C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0022-328X(96)06525-4

The mononuclear complexes [FeCpI(CO)₂] 1, [FeCp(CO)₂(η¹-dppm)]I 2, [FeCp(CO)(η²-dppm)]I 3, [FeCp(CO)₂(η¹-dppen)]I 5 and [FeCp(CO)(η²-dppen)]I 6 [dppen = Ph₂PC(=CH₂)PPh₂] have been synthesised and reacted with [Rh₂Cl₂(CO)₄] to produce heterobimetallic complexes of the type [CpFe(μ-CO)₂(μ-PP)RhX₂] (X = Cl or I). The structure of [CpFe(μ-CO)₂{μ-Ph₂PCH₂PPh₂}RhI₂] 4 has been determined by X-ray crystallography.

Full text of DOI:10.1016/S0022-328X(96)06525-4

Products guided by the article

Product name:[(C5H5)Fe(CO)(η(2)-dppm)]I

Cas No:36580-20-8

R&D Labs maybe for 36580-20-8

Yancheng Smiling Imp & Exp Co., Ltd.

Contact:+86-515-83173586

Address:Rm1207, BLD#03, Phoenix Plaza, Juheng Road, Yancheng, Jiangsu, P.R. China
Jiangsu Seed Chem Co.,Ltd.

Contact:86-513-84128750/13773795976

Address:No.48.Youyi West Road ,Rudong Development Zone,Jiangsu Province,China
Changzhou Litong Chemical Co., Ltd.

website:http://www.litonchem.com/

Contact:+86-519-86301238

Address:Laoba Rd, Hutang town Changzhou Jiangsu
Hebei yanxi chemical co.,LTD.

website:https://en.yan-xi.com/

Contact:+86 17531190177--

Address:Zhang zhe, guangzong county, xingtai city, hebei province
CHEM PLUS

Contact:0027-717-456976

Address:2ND FLOOR, 325 VAUSE ROAD, OVERPORT, 4001, SOUTH AFRICA

Relevant to this article

Optimization of a synthetic arginine receptor. Systematic tuning of noncovalent interactions

Doi:10.1021/jo0156161
(2001)
Chiral aminoalcohols with a menthane skeleton as catalysts for the enantioselective addition of diethylzinc to benzaldehyde

Doi:10.1016/S0957-4166(01)00206-3
(2001)
Total synthesis of TMC-95A and -B via a new reaction leading to Z-enamides. Some preliminary findings as to SAR

Doi:10.1021/ja049821k
(2004)
Structural basis for rational design of inhibitors targeting Trypanosoma cruzi Sterol 14α-demethylase: Two regions of the enzyme molecule potentiate its inhibition

Doi:10.1021/jm500739f
(2014)
Synthesis and molecular structure of [Pd{CH₂CH₂C(O)Me}(HL)][BAr′₄] (HL = 6-Me-2,2′-bipyridine, Ar′ = 3,5-(CF₃)₂C₆H₃), an intermediate relevant to ethene/CO copolymerization

Doi:10.1021/om010278f
(2001)
Discovery of 5-(4-hydroxy-6-methyl-2-oxo-2H-pyran-3-yl)-7-phenyl-(E)-2,3,6,7-tetrahydro-1,4-thiazepines as a new series of apoptosis inducers using a cell- and caspase-based HTS assay

Doi:10.1016/j.bmcl.2007.05.098
(2007)

Article Doi