Chemical Communications p. 5518 - 5521 (2021)
Update date:2022-07-30
Topics:
Hasenbeck, Max
Wech, Felix
Averdunk, Arthur
Becker, Jonathan
Gellrich, Urs
We herein report the reaction of arylallenes with tris(pentafluorophenyl)borane that yields pentafluorophenyl substituted indenes. The tris(pentafluorophenyl)borane induces the cyclization of the allene and transfers a pentafluorophenyl ring in the course of this reaction. A Hammett plot analysis and DFT computations indicate a 1,1-carboboration to be the C-C bond-forming step.
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