Catalytic enantioselective stereoablative alkylation of 3-halooxindoles: Facile access to oxindoles with c3 all-carbon quaternary stereocenters

DOI: 10.1002/anie.200902943

Source and publish data:

Angewandte Chemie - International Edition p. 8037 - 8041 (2009)

Update date:2022-07-30

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Authors:

Ma, Sandy

Han, Xiaoqing

Krishnan, Shyam

Virgil, Scott C.

Stoltz, Brian M.

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Article abstract of DOI:10.1002/anie.200902943

From 2 to 1! Racemic tertiary halooxindoles proceed to enantioenriched oxindoles bearing all-carbon quaternary stereocenters as a result of a catalytic enantioselective stereoablative process (see scheme). The application of this procedure allows for the

Full text of DOI:10.1002/anie.200902943

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