Tetrahedron Letters p. 4353 - 4356 (1989)
Update date:2022-08-05
Topics:
Breslow, Ronald
Chung, Shin
Rearrangement of an N-hydroxyimidazole to a side-chain functionalized derivative permits easy synthesis of a puported chymotrypsin mimic that contains a "catalytic triad" as part of a cyclodextrin molecule.Contrary to the previous claims, the added functional groups do not play a role in the cyclodextrin reaction with a typical substrate, but in fact slow the reaction because of steric hindrance.
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