Tetrahedron Letters p. 1711 - 1712 (1985)
Update date:2022-07-29
Topics:
Beltran, A. Murillo
Klaebe, A.
Perie, J. J.
Basic hydrolysis of paranitrophenylphosphate in acetonitrile of low water content (0.02 to 0.5 M) is an unimolecular process, with likely a phosphenium cation as intermediate.Comparison with reaction in water - also occuring through an unimolecular process - indicates that the large rate enhancement in CH3CN (3E6 for
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