Journal of the Chemical Society. Chemical communications p. 616 - 617 (1989)
Update date:2022-08-02
Topics:
Banwell, Martin G.
Collis, Maree P.
Crisp, Geoffrey T.
Lambert, John N.
Reum, Monica E.
Scoble, Judith A.
The bromotropolones (1), (2), and (3) cross-couple with organostannanes in the presence of palladium(O) to produce alkyl, alkenyl, or aryl substituted tropolones; the methodology has been applied to the synthesis of the monoterpenes β-dolabrin (4), β-thujaplicin (5), 7-methoxy-4-isopropyltropolone (7), and β-thujaplicinol (8).
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