Syntheses of low-valent nitrosyl complexes of rhenium and X-ray structure of trans-2 with nitrosyl derived nitrates

DOI: 10.1016/0022-328X(92)83275-M

Source and publish data:

Journal of Organometallic Chemistry p. C56 - C59 (1992)

Update date:2022-09-26

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Authors:

Wang, Yu

Silva, Joao J.R. Frausto Da

Pombeiro, Armando J.L.

Pellinghelli, Maria Angela

Tiripicchio, Antonio

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Article abstract of DOI:10.1016/0022-328X(92)83275-M

The nitrosyl complexes trans-A2 (1; A = BF4 or NO3; dppe = Ph2PCH2CH2PPh2) and trans- (2) have been prepared from the reactions of NO or NO with trans-. an unusual facile oxidation of NO to nitrate is involved in the formation of (1, A = NO3), the X-ray structure of which is reported.

Full text of DOI:10.1016/0022-328X(92)83275-M

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