Chemical Communications p. 3196 - 3199 (2015)
Update date:2022-09-26
Topics:
Lamb, Brian M.
Barbas, Carlos F.
A routine thioketal protecting group reacts rapidly and selectively with singlet oxygen to reveal ketone products in good (aryl 1,3-dithiolane) to excellent (aryl 1,3-oxathiolane) yields. Arylthiolanes are stable to biologically relevant reactive oxygen species and can be used as a light-activated gating mechanism for activating fluorescent sensors or small molecule prodrugs.
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