Tetrahedron Letters p. 3275 - 3278 (1997)
Update date:2022-08-04
Topics:
Kakiya, Hirotada
Inoue, Rie
Shinokubo, Hiroshi
Oshima, Koichiro
Treatment of dibromomethyltrialkylsilanes with butylmagnesium bromide in the presence of a catalytic amount of manganese(II) chloride provided (E)-1-trialkylsilyl-1-pentenes with high stereoselectivity in good yields.
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