Journal of Organometallic Chemistry p. 275 - 279 (1996)
Update date:2022-07-30
Topics:
Molander, Gary A.
Winterfeld, Joern
This communication presents a study of the scope of the catalytic hydrogenation and hydrosilylation of chiral exomethylene-substituted cyclopentanes and cyclohexanes utilizing the organolanthanide precatalysts Cp2* LnCH(SiMe3)2 (Cp* = C5Me5; Ln = Sm, Yb). Both reaction types are sterically driven and lead to the cis-diastereomer as the major product. Additionally, the hydrosilylation is regiospecific, the silane being placed exclusively at the terminal position of the double bond.
View MoreChangzhou BaoKang Pharmaceutical & Chemical Co., Ltd
Contact:(86) 519-88782201 88784080 88785278
Address:Henglin town, changzhou,Jiangsu
Chengdu Cogon Bio-tech Co., Ltd.
Contact:86-28-85171192
Address:NO.52.YongFeng Rd. Chengdu,610041,P.R.China.
Zhejiang PRIMAR Import & Export Trade Co., Ltd.
Contact:86-570-3630818
Address:No.1Puzhuyuan,Quhua,Zhejiang Province,China324004
Contact:86-571-86737118-8689
Address:No.69, 12 Street, HEDA, Hangzhou, Zhejiang, China
Contact:+86-574- 87178138; 87297407
Address:No. 809, Liudingxingzuo, cangsong road, Ningbo, China
Doi:10.1021/ja00474a037
(1978)Doi:10.1016/S0040-4039(00)77642-8
(1993)Doi:10.1021/jo4009589
(2013)Doi:10.1055/s-0036-1589523
(2018)Doi:10.1021/jo4011848
(2013)Doi:10.1002/chem.201202698
(2013)