THE EPOXYHEXENYNE - VINYLFURAN TRANSFORMATION: EVIDENCE FOR CARBENE INTERMEDIATES

DOI: 10.1016/S0040-4039(00)96181-1

Source and publish data:

Tetrahedron Letters p. 2685 - 2688 (1987)

Update date:2022-08-02

Topics:

Authors:

Eberbach, Wolfgang

Roser, Joachim

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Article abstract of DOI:10.1016/S0040-4039(00)96181-1

The thermal conversion of the (Z)-epoxyhexenynes 3a/3b into three pairs of isomeric vinylfuran derivatives is explained on the basis of a multistep mechanism with butenynyl carbonyl ylides, cycloallenes and vinyl carbenes as intermediates.

Full text of DOI:10.1016/S0040-4039(00)96181-1

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