Journal of the American Chemical Society p. 14391 - 14393 (2010)
Update date:2022-08-03
Topics:
Shang, Rui
Yang, Zhi-Wei
Wang, Yan
Zhang, Song-Lin
Liu, Lei
Pd-catalyzed decarboxylative cross-couplings of 2-(2-azaaryl)acetates with aryl halides and triflates have been discovered. This reaction is potentially useful for the synthesis of some functionalized pyridines, quinolines, pyrazines, benzoxazoles, and benzothiazoles. Theoretical analysis shows that the nitrogen atom at the 2-position of the heteroaromatics directly coordinates to Pd(II) in the decarboxylation transition state.
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