Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics p. 1196 - 1199 (1984)
Update date:2022-08-05
Topics:
Henglein
Fischer
Chloroform is decomposed by irradiation with ultrasonic waves to yield a large number of products. The major products are various unsaturated compounds. Decomposition occurs only in the presence of a monoatomic- or diatomic gas. Free radicals and carbenes are postulated as intermediates of sonolysis which can only be scavenged by volatile additives such as O//2 or c-hexene. In the presence of 10% c-hexene, the rate of sonolysis of chloroform is increased and various additional products are formed. Pure c-hexene is decomposed at a much lower rate than chloroform. The sonolysis of chloroform proceeds at a rate comparable to that of water.
Heliosense Biotechnologies, Inc.
website:https://www.heliosense.com/
Contact:+86-592-5667290
Address:Xiamen Torch Hi-tech Zone Venture Weiye Building S506
Chengdu Boon Stream Chemical Industry Co.,Ltd.
Contact:+86-28-83156758
Address:No.859,Dongzikou Road,Jinniu District,Chengdu,Sichuan,P.R.China
Contact:+86-512-69561895
Address:No.111, Building A4, 218 Xinghu Street, Suzhou Industrial Park, P. R. China
Yingkou Sanzheng New Technology Chemical Industry Co., Ltd.
Contact:+86-417-2927806
Address:yingkou
website:http://www.ringchemicals.com/
Contact:+1-416-493-6870
Address:Toronto, Canada
Doi:10.1128/AAC.00289-07
(2007)Doi:10.1021/jm00313a002
(1967)Doi:10.1021/jo010637g
(2002)Doi:10.1016/j.saa.2007.03.041
(2008)Doi:10.1021/jo00931a033
(1974)Doi:10.1002/anie.200701931
(2007)
