Electron-transfer Chain Catalysis of Substitution Reactions. Experimental Evidence for the SON2 Mechanism

DOI: 10.1039/c39800001187

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Journal of the Chemical Society. Chemical communications p. 1187 - 1188 (1980)

Update date:2022-08-05

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Authors:

Eberson, Lennart

Joensson, Lennart

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Article abstract of DOI:10.1039/c39800001187

Two possible cases of an oxidative electron-transfer chain catalysis mechanism, the S_ON2 mechanism, are presented: the anionic 'oxidation' of 4-fluoroanisole in the presence of acetate ion to give 4-acetoxyanisole, and the Cu^III 'oxidation' of chloro- and fluoro-benzene in the presence of water to give phenol.

Full text of DOI:10.1039/c39800001187

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