Complex Formation between Bisparaphenylene-(3n+4)-crown-n Ethers and the Paraquat and Diquat Dications

DOI: 10.1039/c39870001066

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1066 - 1069 (1987)

Update date:2022-08-05

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Authors:

Ashton, Peter R.

Slawin, Alexander M. Z.

Spencer, Neil

Stoddart, J. Fraser

Williams, David J.

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Article abstract of DOI:10.1039/c39870001066

U.v. and n.m.r. spectroscopic investigations in solution have been employed to assess the ability of a series (n=7-12) of bisparaphenylene-(3n+4)-crown-n ethers to form stable 1:1 complexes with ²⁺ and ²⁺ dications; these mappings of molecular recognition are supported by fast atom bombardment mass spectrometry of the 1:1 complexes with both 2 and 2, and a single crystal X-ray structure analysis of 2.

Full text of DOI:10.1039/c39870001066

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