Tetrahedron Letters p. 1679 - 1682 (1992)
Update date:2022-08-05
Topics:
Gopalan
Prieto
Mueller
Peters
The cyclization of a number of functionalized polyenes with mercuric triflate-N,N-dimethylaniline complex (Nishizawa's reagent) to give bicyclic or tricyclic products has been studied. Suitably positioneal internal nucleophiles, such as carbonyl, hydroxy and β-ketoester groups were found to participate to varying extent, in the termination of these cyclizations.
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