COPPER(I) IODIDE ASSISTED REACTION OF NONACTIVATED IODOARENES WITH SODIUM TRIFLUOROACETATE IN HEXAMETHYLPHOSPHORIC TRIAMIDE. NUCLEAR TRIFLUOROMETHYLATION AND DIARYL ETHER FORMATION

DOI: 10.1246/cl.1982.135

Source and publish data:

Chemistry Letters p. 135 - 136 (1982)

Update date:2022-09-26

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Authors:

Suzuki, Hitomi

Yoshida, Yoshiki

Osuka, Atsuhiro

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Article abstract of DOI:10.1246/cl.1982.135

Polymethyliodobenzenes react with sodium trifluoroacetate, in the presence of copper(I) iodide, in hexamethylphosphoric triamide at 150-180 deg C, giving a mixture of the corresponding polymethylbenzotrifluoride, parent hydrocarbon, and bis(polymethylphenyl) ether.

Full text of DOI:10.1246/cl.1982.135

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