Tetrahedron Letters p. 2207 - 2208 (1989)
Update date:2022-08-02
Topics:
Nzabamwita, Gaspard
Kolani, Bate
Jousseaume, Bernard
Reactions of 6-silyloxy-6-alkyl-fulvenes with dimethyl acetylenedicarboxylate, maleic anhydride and 2-chloroacrylonitrile resulted in the formation of expected 7-substituted bicyclo<2.2.1>hepta-2,5-diene and hept-5-ene derivatives.Treatment of these adducts with Bu4NF produced the 7-norborn-5-enyl and 7-norborno-2,5-dienyl aldehydes and ketones in good yields.
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