Regioselective Synthesis of β,γ-Unsaturated Acids by the Electrochemical Carboxylation of Allylic Bromides Using a Reactive-metal Anode

DOI: 10.1016/0040-4039(95)00537-M

Source and publish data:

Tetrahedron Letters p. 3345 - 3348 (1995)

Update date:2022-08-04

Topics:

Authors:

Tokuda, Masao

Kabuki, Takashi

Katoh, Yoshitaka

Suginome, Hiroshi

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Article abstract of DOI:10.1016/0040-4039(95)00537-M

Electrolysis of γ-mono and disubstituted allylic bromides in the presence of atmospheric pressure of carbon dioxide using a platinum cathode and a magnesium anode gave regioselectively the corresponding γ-mono and disubstituted β,γ-unsaturated carboxylic acids in 34-71percent yields.

Full text of DOI:10.1016/0040-4039(95)00537-M

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