
Canadian Journal of Chemistry p. 655 - 665 (1995)
Update date:2022-08-03
Topics:
Zamir
Nedea
Zhou
Belair
Caron
Sauriol
Jacqmain
Jean
Garneau
Mamer
The structures and stereochemistry of 14 taxanes isolated from Taxus canadensis have been rigorously established by high-resolution NMR techniques and mass spectrometry. Taxus canadensis is the only yew that accumulates 9-dihydro-13-acetylbaccatin III (also called 7,9-deacetylbaccatin VI) as the most abundant taxane. Five 9-dihydrotaxanes derived from the Canadian yew are novel natural products not reported in the needles of other species of yew.
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