Chemical Communications p. 12092 - 12095 (2017)
Update date:2022-08-05
Topics:
Yang, Zhantao
Yang, Chun-Hua
Chen, Shiqi
Chen, Xixi
Zhang, Litian
Ren, Huijun
A direct and catalyst-free annulative thioboration of unfunctionalized olefins has been developed. In the presence of BCl3 as the sole boron source, the boryl group and thiol group are added to the C-C double bonds simultaneously. The boronic acids obtained can be protected to form synthetically ubiquitous pinacol boronate esters.
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