Palladium-Catalyzed Coupling between Organic Halides and Organotin Compounds Involving C-N Unsaturated Bonds at the Reaction Centers

Article abstract of DOI:10.1246/bcsj.59.677

Imidoyl chlorides were good substrates which can react with a variety of organotin compounds to give ketimines in the presence of a catalytic amount of palladium complex.Under similar conditions, C-tributylstannyl imines did not give the products except with 2-(tributylstannyl)benzothiazole, -benzoxazole, and 1-methyl-2-(tributylstannyl)imidazole.And N-tributylstannyl imines could not be utilized.