Tetrahedron Letters p. 5211 - 5214 (1982)
Update date:2022-09-26
Topics:
Di Maio, G.
Vecchi, E.
Zeuli, E.
Kinetic evidence shows that the two groups of a δ-ketoester can interact in the transition state of a Grignard reaction.This promotes high stereoselectivity by chiral center far from the ketonic group and produces good correlations between stereoselection and electronic effects of substituents.
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