THE REACTION OF TRIHYDROBISTRIPHENYLPHOSPHINE IRIDIUM IrH3(PPh3)2 WITH DIAZONIUM SALTS

DOI: 10.1016/S0022-328X(00)85705-8

Source and publish data:

Journal of Organometallic Chemistry p. 99 - 106 (1982)

Update date:2022-08-05

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Authors:

Angoletta, Maria

Caglio, Giorgio

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Article abstract of DOI:10.1016/S0022-328X(00)85705-8

The reaction of IrH3(PPh3)2 with p-substituted aryldiazonium salts gives the compounds ⁺BF4^- at low temperature (-10 deg C) and the o-metalated complexes (R=F, OCH3) at 40-50 deg C.The reactions of the o-metalated complexes with CO, PPh3, NaI and HCl have been studied.

Full text of DOI:10.1016/S0022-328X(00)85705-8

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