KINETIC RESOLUTION OF LACTONES BY ENANTIOSELECTIVE PROTONATION OF THE CORRESPONDING CARBOXYLATE WITH A CHIRAL ACID

DOI: 10.1016/S0040-4039(00)85216-8

Source and publish data:

Tetrahedron Letters p. 5381 - 5382 (1986)

Update date:2022-08-03

Topics:

Authors:

Fuji, Kaoru

Node, Manabu

Murata, Makoto

Terada, Shunji

Hashimoto, Keiji

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Article abstract of DOI:10.1016/S0040-4039(00)85216-8

Racemic lactones were optically activated through the hydrolysis with sodium hydroxide followed by the partial neutralisation with (1S)-(+)-10-camphorsulfonic acid in ethanol to afford R- or S-isomer with 99 - 38percent ee.

Full text of DOI:10.1016/S0040-4039(00)85216-8

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