Tetrahedron Letters p. 5727 - 5730 (1983)
Update date:2022-08-03
Topics:
Adam, Waldemar
Beinhauer, Axel
de Lucchi, Ottorino
Rosenthal, Robert J.
The dienophiles triazolinedione, singlet oxygen and in part tetracyanoethylene cycloadd to bicyclo<2.1.0>pent-2-ene (1) across the central ?-bond to give bicyclo<2.2.1>heptene-type adducts, while the dipoles phenyl azide, benzonitrile oxide and diphenyldiazomethane cycloadd at the ?-bond with expected exo stereochemistry.
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(2003)
