
Tetrahedron p. 9511 - 9516 (1994)
Update date:2022-08-05
Topics:
Grossi, Loris
The oxidation reaction of aniline by tertiary hydroperoxides, induced photochemically, was studied.The peculiar radical intermediates, nitroxides and peroxy radicals, involved in the reaction mechanism were detected and identified by EPR spectroscopy.The presence of these intermediates confirm that PhNO is the first product of the oxidation of aniline and the PhNH<*> radical as its precursor.
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