New Syntheses of Mixed Peroxides under Gif-Barton Oxidation of Alkylbenzenes, Conjugated Alkenes and Alkanes; a Free-radical Mechanism

DOI: 10.1039/c39940001823

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1823 - 1824 (1994)

Update date:2022-07-30

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Authors:

Minisci, Francesco

Fontana, Francesca

Araneo, Silvia

Recupero, Francesco

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Article abstract of DOI:10.1039/c39940001823

Syntheses of mixed peroxides are performed under Gif oxidation of alkylaromatics, electron-rich conjugated alkenes (styrene, α-methylstyrene) or cyclohexane and acrylonitrile; chemical and kinetic evidence support a free-radical redox chain mechanism.

Full text of DOI:10.1039/c39940001823

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